The Synthesis of Alkyltin Halides by Direct Reaction between Tin and Alkyl Halides
نویسندگان
چکیده
منابع مشابه
Direct Etherification of Alkyl Halides by Sodium Hydride in the Presence of N,N-Dimethylformamide Direct Etherification of Alkyl Halides
SYNLETT 2007, No. 17, pp 2695–269816.10.2007 Advanced online publication: 25.09.2007 DOI: 10.1055/s-2007-991068; Art ID: U07007ST © Georg Thieme Verlag Stuttgart · New York Abstract: A novel synthetic method for the preparation of various alkyl ethers is described. The reaction between alkyl halides and sodium hydride in the presence of N,N-dimethylformamide afforded the corresponding symmetric...
متن کاملA mild and efficient procedure for the synthesis of ethers from various alkyl halides
A simple, mild and practical procedure has been developed for the synthesis of symmetrical and unsymmetrical ethers by using DMSO, TBAI in the presence of K2CO3. We extended the utility of Potassium carbonate as an efficient base for the preparation of ethers. A wide range of alkyl aryl and dialkyl ethers are synthesized from treatment of aliphatic alcohols and phenols with various alkyl hali...
متن کاملPalladium-catalyzed intermolecular Heck reaction of alkyl halides.
Intermolecular Heck reaction of common alkyl halides, a longstanding problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary and secondary alkyl halides are suitable for coupling with aromatic olefins. Single electron transfer from (dppf)Pd(0) to alkyl halide initiated the catalytic cycle and gave alkyl radicals.
متن کاملChiral Alkyl Halides: Underexplored Motifs in Medicine
While alkyl halides are valuable intermediates in synthetic organic chemistry, their use as bioactive motifs in drug discovery and medicinal chemistry is rare in comparison. This is likely attributable to the common misconception that these compounds are merely non-specific alkylators in biological systems. A number of chlorinated compounds in the pharmaceutical and food industries, as well as ...
متن کاملDirect carbamoylation of aryl halides.
[reaction: see text] A carbamoylsilane is shown to carry out the direct carbamoylation of aryl chlorides, bromides, and iodides under catalysis by phosphinepalladium(0) complexes.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1962
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.35.208